If its icing on the road that is your concern...a thermocouple will not react fast enough to give you any, useful, real time information. No better than the weather channel, before you leave.
Ambient air temperature can change quickly, compared to the surface ground temp. Those temps usually lead and lag each other.
Knowing the current air temp, only for a moment, only says so much.
If there is a threat of icing, there it is. Pushing that limit on my local roads, has racked up quite a toll. Especially first and last frost...there will be an example, every time.
Besides that...the drier the sensor, the more accurate. The less it touches a heat sink/source the better.
Mount it with the leads facing down, if possible.
Whatever you glue or tie it with/to, will be a heat sink...and affect reaction time/accuracy.
Remember... it is dry bulb temperature that you are concerned with for freezing...wet bulb for comfort...in a practical sense.
Check the weather, and prepare accordingly...black ice is where you least expect it sometimes.